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- W2021102232 abstract "Hydrooligomerizations and polymerizations of cyclopentene were carried out using CS, C2 and C2v symmetric zirconocenes and methylaluminoxane as catalyst. The structure of the hydrotrimers was investigated by one- and twodimensional NMR spectroscopy and correlated to the structure of the polymers. The assignments for the 13C-NMR spectrum of the cis-1,3-enchained hydrotrimer made by Collins [3] are corrected. Cis-1,3-enchainment of the configurational base units in the poly(cyclopentenes) is confirmed. rac-[Me2Si(Ind)2]ZrCl2/MAO catalysis features crystalline polymers and the erythrodiisotactic hydrotetramer indicating highly stereoselective insertion. Cp2ZrCl2/MAO and [Ph2C(Fluo)(Cp)]ZrCl2/MAO show none or low stereoselectivity respectively yielding amorphous polymers and both of the diastereomeric hydrotetramers." @default.
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- W2021102232 date "1995-06-01" @default.
- W2021102232 modified "2023-10-15" @default.
- W2021102232 title "Polymerization with metallocene catalysts. Hydrooligomerization and NMR investigations concerning the microstructure of poly(cyclopentenes)" @default.
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- W2021102232 doi "https://doi.org/10.1002/masy.19950950115" @default.
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