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- W2021104294 endingPage "575" @default.
- W2021104294 startingPage "527" @default.
- W2021104294 abstract "4,4′-Dithiodipyridine (dtdp), also termed 4,4′-dipyridyldisulfide, is a bridging ligand of the 4,4′-bipyridine type. The introduction of the disulfide moiety inevitably leads to a relatively rigid angular structure, which exhibits axial chirality. More than 90 metal complexes containing the dtdp ligand have been crystallographically characterised until now. This review focuses on the preparation and structural diversity of discrete and polymeric metallosupramolecular assemblies constructed from dtdp as bridging ligands. These encompass metallamacrocycles with M2L2 topology and coordination polymers with periodicity in one or two dimensions. One-dimensional coordination polymers represent the vast majority of the metallosupramolecular structures obtained from dtdp. These include repeated rhomboids, zigzag, helical and arched chains among other types. In this contribution, we make an attempt to provide a comprehensive account of the structural data that are currently available for metallosupramolecular assemblies based on the bent bridging ligand dtdp." @default.
- W2021104294 created "2016-06-24" @default.
- W2021104294 creator A5007273245 @default.
- W2021104294 creator A5037346929 @default.
- W2021104294 creator A5081453699 @default.
- W2021104294 date "2013-05-21" @default.
- W2021104294 modified "2023-09-30" @default.
- W2021104294 title "Structural Diversity of Metallosupramolecular Assemblies Based on the Bent Bridging Ligand 4,4′-Dithiodipyridine" @default.
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