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- W2021107688 abstract "Phenylenedioxydiacetamides are examples of noncyclic ionophors that are able to form 2:1 complexes with the cations Ca 2+ and K + in acetone, methylene chloride or acetonitrile solution. The chelation abilities and coordination modes of 12 derivatives were investigated systematically by IR, 1 H NMR and 13 C NMR spectroscopy. The results indicate that only the 1,2-phenylenedioxydiacetam ides function as ligands; while the 1,3-derivatives do not coordinate. The ionophors 1-8 act as tetradentate chelating ligands with all four oxygen atoms involved in bonding to the cation. Irrespective of its charge, each cation is coordinated by two ionophors." @default.
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- W2021107688 date "1984-10-01" @default.
- W2021107688 modified "2023-09-26" @default.
- W2021107688 title "1H and 13C NMR Spectroscopic Studies of the Complexation of Phenylenedioxydiacetamides with Calcium and Potassium Cations in Solution" @default.
- W2021107688 doi "https://doi.org/10.1515/znb-1984-1013" @default.
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