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• W2021107738 abstract "Shake-up transitions occurring upon core photoionization in the SF6 molecule have been studied experimentally and theoretically. The S 2p, S 2s and F 1s shake-up satellite photoelectron spectra were measured using Al Ka radiation at 1487 eV photon energy. They have been interpreted with the aid of ab initio configuration interaction calculations in the sudden-limit approximation. For the S 2p spectrum, conjugate shake-up transitions were also calculated. Clear evidence of conjugate processes is observed in the S 2p shake-up spectrum measured at 230 eV photon energy. The experimental and theoretical S 2p and S 2s shake-up spectra show very similar structures mainly due to orbital relaxation involving S 3s and 3p participation. For the calculation of the F 1s shake-up spectrum, the symmetry lowering of the molecule in the final states was considered, resulting in a good agreement with the experiment." @default.
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• W2021107738 date "2009-02-16" @default.
• W2021107738 modified "2023-09-25" @default.
• W2021107738 title "Shake-up transitions in S 2p, S 2s and F 1s photoionization of the SF₆molecule" @default.
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• W2021107738 doi "https://doi.org/10.1088/0953-4075/42/5/055102" @default.
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