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- W2021115087 endingPage "5322" @default.
- W2021115087 startingPage "5316" @default.
- W2021115087 abstract "The orientation of allyl alcohol (CH2=CHCH2OH), propargyl alcohol (CH 3/4 CCH2OH), and their surface alkoxy groups has been examined on Ag(110) using near edge x‐ray absorption fine structure (NEXAFS) measurements. The planes containing the π* orbitals of allyl alcohol and its alkoxy species, allyloxy (CH2=CHCH2O−), are tilted 26±4° and 32±5° from the surface normal, respectively. Allyl alcohol itself shows no azimuthal ordering, but the π* orbital in allyloxy is azimuthally oriented 33±15° from the close‐packed direction ([11̄0] azimuth). Propargyl alcohol is randomly oriented on the Ag(110) surface. Its alkoxy group, propargyloxy (CH 3/4 CCH2O−), is strongly oriented with the triple bond axis parallel to the plane of the surface and directed along the [001] azimuth, perpendicular to the troughs. The position of the σ* resonances indicate that no loss of the allylic hydrogen has occurred and that the double and triple bonds are slightly, but not significantly, perturbed from their normal gas phase bond lengths." @default.
- W2021115087 created "2016-06-24" @default.
- W2021115087 creator A5042069920 @default.
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- W2021115087 date "1988-10-15" @default.
- W2021115087 modified "2023-09-26" @default.
- W2021115087 title "π bonded intermediates in alcohol oxidation: Orientations of allyloxy and propargyloxy on Ag(110) by near edge x‐ray absorption fine structure" @default.
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- W2021115087 doi "https://doi.org/10.1063/1.455622" @default.
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