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- W2021115387 abstract "Two processes affecting the signal of amperometric enzyme electrodes were investigated, namely the consumption of substrate in the bulk solution and the release of electrochemically active product from the enzyme layer. A cobalt phthalocyanine modified graphite composite electrode covered with an immobilized cholinesterase layer was used as a model system. The influence of substrate concentration, electrode potential and mass transfer was evaluated. The fluxes of substances in the biocatalytic layer were described with the help of Michaelis-Menten kinetics. Obtained apparent constants K and maximal fluxes J were utilized for the construction of theoretical equations which provided relative changes in signal as functions of substrate concentration. The predicted relative drifts of the signal corresponded with experimental values." @default.
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- W2021115387 date "1993-11-01" @default.
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- W2021115387 title "Effects disturbing signal stability of amperometric biosensors for long-term measurements" @default.
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- W2021115387 doi "https://doi.org/10.1016/0302-4598(93)80032-p" @default.
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