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- W2021128412 abstract "Observation of two weak absorption lines from the E (K=1) level and one intense feature from A (K=0) for degenerate modes ν4 and ν6 of CH3F provides direct spectral evidence that CH3F isolated in p-H2 rotates about only its symmetry axis, and not about the other two axes. An interaction between A and E vibrational levels caused by the partially hindered spinning rotation is proposed. Conversion of nuclear spin between A and E components of CH3F is rapid when p-H2 contains some o-H2, but becomes slow when the proportion of o-H2 is much decreased." @default.
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- W2021128412 date "2008-09-08" @default.
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- W2021128412 title "Direct spectral evidence of single-axis rotation and <i>ortho</i>-hydrogen-assisted nuclear spin conversion of CH3F in solid <i>para</i>-hydrogen" @default.
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- W2021128412 doi "https://doi.org/10.1063/1.2975340" @default.
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