FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2021129620> ?p ?o ?g. }

• W2021129620 endingPage "2839" @default.
• W2021129620 startingPage "2833" @default.
• W2021129620 abstract "Abstract There has been an ongoing debate regarding the mechanism that causes rate retardation phenomena observed in some reversible addition‐fragmentation transfer (RAFT) polymerization systems. Some attribute the retardation to slow fragmentation of adduct radicals, others attribute it to fast fragmentation coupled with cross‐termination between propagating and adduct radicals. There exists a difference of six orders of magnitude (10 −2 versus 10 4 /s) in the reported values of the fragmentation rate constant ( k f0 ) for virtually similar RAFT systems of PStSC · (Ph)SPSt. In this communication, we explain the estimates of k f ∼ 10 4 /s and the choices of the rate constant in modeling based on experimental polymerization rate and radical concentration data. The use of k f ∼ 10 −2 /s in the model results in a calculated adduct radical concentration level of 10 −4 to 10 −3 mol/L, which appears to directly contradict the reported electron spin resonance (ESR) data in the range of <10 −6 mol/L. We hope that this open discussion can stimulate more effort to resolve this outstanding difference. © 2003 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 41: 2833–2839, 2003" @default.
• W2021129620 created "2016-06-24" @default.
• W2021129620 creator A5009074004 @default.
• W2021129620 creator A5029514198 @default.
• W2021129620 creator A5036173839 @default.
• W2021129620 creator A5050983100 @default.
• W2021129620 creator A5062985611 @default.
• W2021129620 creator A5071994497 @default.
• W2021129620 date "2003-08-01" @default.
• W2021129620 modified "2023-10-18" @default.
• W2021129620 title "A difference of six orders of magnitude: A reply to ?the magnitude of the fragmentation rate coefficient?" @default.
• W2021129620 cites W1964918647 @default.
• W2021129620 cites W1968486804 @default.
• W2021129620 cites W1982863731 @default.
• W2021129620 cites W2003033997 @default.
• W2021129620 cites W2019346692 @default.
• W2021129620 cites W2020407639 @default.
• W2021129620 cites W2027761597 @default.
• W2021129620 cites W2031912582 @default.
• W2021129620 cites W2032884764 @default.
• W2021129620 cites W2036333105 @default.
• W2021129620 cites W2036529073 @default.
• W2021129620 cites W2064293382 @default.
• W2021129620 cites W2072047249 @default.
• W2021129620 cites W2089606220 @default.
• W2021129620 cites W2128987968 @default.
• W2021129620 cites W2135649714 @default.
• W2021129620 cites W2139414379 @default.
• W2021129620 cites W2139932144 @default.
• W2021129620 cites W2150184000 @default.
• W2021129620 doi "https://doi.org/10.1002/pola.10853" @default.
• W2021129620 hasPublicationYear "2003" @default.
• W2021129620 type Work @default.
• W2021129620 sameAs 2021129620 @default.
• W2021129620 citedByCount "121" @default.
• W2021129620 countsByYear W20211296202012 @default.
• W2021129620 countsByYear W20211296202013 @default.
• W2021129620 countsByYear W20211296202014 @default.
• W2021129620 countsByYear W20211296202015 @default.
• W2021129620 countsByYear W20211296202016 @default.
• W2021129620 countsByYear W20211296202017 @default.
• W2021129620 countsByYear W20211296202018 @default.
• W2021129620 countsByYear W20211296202019 @default.
• W2021129620 countsByYear W20211296202020 @default.
• W2021129620 countsByYear W20211296202021 @default.
• W2021129620 countsByYear W20211296202022 @default.
• W2021129620 crossrefType "journal-article" @default.
• W2021129620 hasAuthorship W2021129620A5009074004 @default.
• W2021129620 hasAuthorship W2021129620A5029514198 @default.
• W2021129620 hasAuthorship W2021129620A5036173839 @default.
• W2021129620 hasAuthorship W2021129620A5050983100 @default.
• W2021129620 hasAuthorship W2021129620A5062985611 @default.
• W2021129620 hasAuthorship W2021129620A5071994497 @default.
• W2021129620 hasConcept C108204754 @default.
• W2021129620 hasConcept C111919701 @default.
• W2021129620 hasConcept C111998727 @default.
• W2021129620 hasConcept C121120078 @default.
• W2021129620 hasConcept C121332964 @default.
• W2021129620 hasConcept C139066938 @default.
• W2021129620 hasConcept C148898269 @default.
• W2021129620 hasConcept C178790620 @default.
• W2021129620 hasConcept C185592680 @default.
• W2021129620 hasConcept C188027245 @default.
• W2021129620 hasConcept C191015642 @default.
• W2021129620 hasConcept C41008148 @default.
• W2021129620 hasConcept C44228677 @default.
• W2021129620 hasConcept C521977710 @default.
• W2021129620 hasConcept C62520636 @default.
• W2021129620 hasConcept C9132879 @default.
• W2021129620 hasConcept C93391505 @default.
• W2021129620 hasConceptScore W2021129620C108204754 @default.
• W2021129620 hasConceptScore W2021129620C111919701 @default.
• W2021129620 hasConceptScore W2021129620C111998727 @default.
• W2021129620 hasConceptScore W2021129620C121120078 @default.
• W2021129620 hasConceptScore W2021129620C121332964 @default.
• W2021129620 hasConceptScore W2021129620C139066938 @default.
• W2021129620 hasConceptScore W2021129620C148898269 @default.
• W2021129620 hasConceptScore W2021129620C178790620 @default.
• W2021129620 hasConceptScore W2021129620C185592680 @default.
• W2021129620 hasConceptScore W2021129620C188027245 @default.
• W2021129620 hasConceptScore W2021129620C191015642 @default.
• W2021129620 hasConceptScore W2021129620C41008148 @default.
• W2021129620 hasConceptScore W2021129620C44228677 @default.
• W2021129620 hasConceptScore W2021129620C521977710 @default.
• W2021129620 hasConceptScore W2021129620C62520636 @default.
• W2021129620 hasConceptScore W2021129620C9132879 @default.
• W2021129620 hasConceptScore W2021129620C93391505 @default.
• W2021129620 hasIssue "18" @default.
• W2021129620 hasLocation W20211296201 @default.
• W2021129620 hasOpenAccess W2021129620 @default.
• W2021129620 hasPrimaryLocation W20211296201 @default.
• W2021129620 hasRelatedWork W1981403462 @default.
• W2021129620 hasRelatedWork W2048284370 @default.
• W2021129620 hasRelatedWork W2377052952 @default.
• W2021129620 hasRelatedWork W2587357194 @default.
• W2021129620 hasRelatedWork W2887495713 @default.
• W2021129620 hasRelatedWork W2913751387 @default.
• W2021129620 hasRelatedWork W3141461669 @default.

• next