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• W2021144190 abstract "Abstract Structures of phosphoranium ions C(PR3)32+ and CR(PR3)2+ reveal partial л character of the PC bonds and molecular orbital calculations confirm that. These two ions are structurally and orbitally similar to well-known trimethylenemethane and allyl species, respectively. We cautiously suggest that possibility of л coordination of phosphoranium ions to transition metals be explored. We carried out molecular orbital calculations on various conformations of two hypothetical complexes, (CO)3Co[C(PH3)3]+ and (PH3)2Pd[CH(PH3)2]+. In the former molecule, Co(CO)3− and C(PH3)32+ groups tend to be staggered, and the P atoms tend to bend toward the Co atom. In the latter molecule, the Pd(PH3)2 group tends to slip toward the phosphoranium P atoms and to stay perpendicular to the mirror plane of CH(PH3)2+; the ligand plane tends to tilt so that the CH group moves away from the Pd atom. In both molecules, the substituents at the phosphoranium P atoms tend to bend away from the metal atom. These predictions agree with structures of various known complexes of transition metals with unsaturated organic ligands." @default.
• W2021144190 created "2016-06-24" @default.
• W2021144190 creator A5075505193 @default.
• W2021144190 date "1982-12-01" @default.
• W2021144190 modified "2023-09-27" @default.
• W2021144190 title "Phosphorus-containing analogues of hydrocarbon ligands. Molecular orbital study of structure and bonding in potential transition-metal complexes containing phosphoranium ions as л ligands" @default.
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• W2021144190 doi "https://doi.org/10.1016/s0022-328x(00)93982-2" @default.
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