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- W2021145187 abstract "Abstract Infrared spectra of gaseous and polycrystalline norbornane [Ricyclo (2.2.1) heptane] and norbornadiene [bicyclo (2.2.1) hepta-2,5-diene] were recorded from 300 to 4000 cm −1 . Raman spectra for the liquid and solid states of both systems were measured from 100 to 4000 cm −1 . Vibrational assignments for these two appreciably strained bicyclic molecules were based upon group frequency correlations, Raman and infrared band intensities and Raman depolarization ratios. Low temperature Raman techniques appear particularly useful in the characterization and assignment of the fundamental vibrations of these systems. Specifically, the observation of weak transitions and the analyses of diffuse spectral regions are facilitated by investigations at liquid nitrogen temperatures. Normal coordinate analyses were performed at various stages of the assignment process in order to access the consistency of the spectral assignments and to identify strongly coupled modes. In these calculations particular emphasis was directed toward the vibrational descriptions provided by the potential energy distributions." @default.
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- W2021145187 date "1973-10-01" @default.
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- W2021145187 title "Interpretation of the vibrational spectra of bicyclic hydrocarbons: norbornane and norbornadiene" @default.
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- W2021145187 doi "https://doi.org/10.1016/0584-8539(73)80167-9" @default.
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