Matches in SemOpenAlex for { <https://semopenalex.org/work/W2021159877> ?p ?o ?g. }
- W2021159877 endingPage "14" @default.
- W2021159877 startingPage "9" @default.
- W2021159877 abstract "Abstract Novel gold(I) complexes based on thiocarbamoyl-pyrazoline ligands were synthetized for the first time and their structural/photophysical properties were determined. Two new monocationic complexes of the type [(Ph)3PAu(L)]PF6 (L = 1-thiocarbamoyl-5-(4-halophenyl)-3-phenyl-pyrazoline) were prepared by reacting (Ph)3PAuCl and ligands in the presence of KPF6 in a 1:1:1 molar ratio in a MeOH/CH2Cl2 (1:1) medium in good yields. The two cationic units from both complexes possess similar structural behaviour around the Au(I) atom which presents a two-coordinate and an almost linear coordination geometry. It was found good correlation between absorption and emission spectra and the photophysical properties were described. The prepared complexes (1 and 2) are representative examples of Au(I)/d10 compounds that present bluish luminescence in the solid state at room temperature when excited at λex = 320 nm. The bluish emission that appears at ca. 415 nm for both cationic complexes was tentatively assigned to the LMCT excitations arising from sulphur based orbitals to the Au(I) atom (S → Au–P). Besides X-ray studies, the complete structural characterization of the prepared compounds also includes elemental analyses, IR spectroscopy, 1H and 13C NMR, UV–Vis absorption and luminescence studies." @default.
- W2021159877 created "2016-06-24" @default.
- W2021159877 creator A5002513274 @default.
- W2021159877 creator A5006472972 @default.
- W2021159877 creator A5007245242 @default.
- W2021159877 creator A5008698309 @default.
- W2021159877 creator A5009134296 @default.
- W2021159877 creator A5010378059 @default.
- W2021159877 creator A5046338798 @default.
- W2021159877 creator A5057390019 @default.
- W2021159877 creator A5071686149 @default.
- W2021159877 creator A5085318794 @default.
- W2021159877 date "2013-10-01" @default.
- W2021159877 modified "2023-10-01" @default.
- W2021159877 title "The first gold(I) complexes based on thiocarbamoyl-pyrazoline ligands: Synthesis, structural characterization and photophysical properties" @default.
- W2021159877 cites W1967178701 @default.
- W2021159877 cites W1969664203 @default.
- W2021159877 cites W1969739157 @default.
- W2021159877 cites W1980565992 @default.
- W2021159877 cites W1986436299 @default.
- W2021159877 cites W1988224385 @default.
- W2021159877 cites W1995657280 @default.
- W2021159877 cites W1998814101 @default.
- W2021159877 cites W2001310886 @default.
- W2021159877 cites W2004123744 @default.
- W2021159877 cites W2005786940 @default.
- W2021159877 cites W2011773329 @default.
- W2021159877 cites W2022467778 @default.
- W2021159877 cites W2025877324 @default.
- W2021159877 cites W2034930174 @default.
- W2021159877 cites W2035727165 @default.
- W2021159877 cites W2039334487 @default.
- W2021159877 cites W2043372237 @default.
- W2021159877 cites W2043624347 @default.
- W2021159877 cites W2045273144 @default.
- W2021159877 cites W2052265901 @default.
- W2021159877 cites W2052869703 @default.
- W2021159877 cites W2055910258 @default.
- W2021159877 cites W2059855067 @default.
- W2021159877 cites W2061393179 @default.
- W2021159877 cites W2065042950 @default.
- W2021159877 cites W2065415421 @default.
- W2021159877 cites W2072292716 @default.
- W2021159877 cites W2084807925 @default.
- W2021159877 cites W2089136778 @default.
- W2021159877 cites W2089795620 @default.
- W2021159877 cites W2090244588 @default.
- W2021159877 cites W2093349581 @default.
- W2021159877 cites W2098832709 @default.
- W2021159877 cites W2105390035 @default.
- W2021159877 cites W2120169533 @default.
- W2021159877 cites W2131350133 @default.
- W2021159877 cites W2144249724 @default.
- W2021159877 cites W2148062424 @default.
- W2021159877 cites W2160539353 @default.
- W2021159877 cites W2318953729 @default.
- W2021159877 cites W2952188512 @default.
- W2021159877 doi "https://doi.org/10.1016/j.poly.2013.07.007" @default.
- W2021159877 hasPublicationYear "2013" @default.
- W2021159877 type Work @default.
- W2021159877 sameAs 2021159877 @default.
- W2021159877 citedByCount "21" @default.
- W2021159877 countsByYear W20211598772014 @default.
- W2021159877 countsByYear W20211598772015 @default.
- W2021159877 countsByYear W20211598772016 @default.
- W2021159877 countsByYear W20211598772017 @default.
- W2021159877 countsByYear W20211598772018 @default.
- W2021159877 countsByYear W20211598772019 @default.
- W2021159877 countsByYear W20211598772020 @default.
- W2021159877 countsByYear W20211598772021 @default.
- W2021159877 countsByYear W20211598772022 @default.
- W2021159877 crossrefType "journal-article" @default.
- W2021159877 hasAuthorship W2021159877A5002513274 @default.
- W2021159877 hasAuthorship W2021159877A5006472972 @default.
- W2021159877 hasAuthorship W2021159877A5007245242 @default.
- W2021159877 hasAuthorship W2021159877A5008698309 @default.
- W2021159877 hasAuthorship W2021159877A5009134296 @default.
- W2021159877 hasAuthorship W2021159877A5010378059 @default.
- W2021159877 hasAuthorship W2021159877A5046338798 @default.
- W2021159877 hasAuthorship W2021159877A5057390019 @default.
- W2021159877 hasAuthorship W2021159877A5071686149 @default.
- W2021159877 hasAuthorship W2021159877A5085318794 @default.
- W2021159877 hasConcept C171250308 @default.
- W2021159877 hasConcept C178790620 @default.
- W2021159877 hasConcept C185592680 @default.
- W2021159877 hasConcept C188027245 @default.
- W2021159877 hasConcept C192562407 @default.
- W2021159877 hasConcept C21951064 @default.
- W2021159877 hasConcept C2780744904 @default.
- W2021159877 hasConcept C2780841128 @default.
- W2021159877 hasConcept C71240020 @default.
- W2021159877 hasConcept C75473681 @default.
- W2021159877 hasConcept C8010536 @default.
- W2021159877 hasConceptScore W2021159877C171250308 @default.
- W2021159877 hasConceptScore W2021159877C178790620 @default.
- W2021159877 hasConceptScore W2021159877C185592680 @default.
- W2021159877 hasConceptScore W2021159877C188027245 @default.
- W2021159877 hasConceptScore W2021159877C192562407 @default.