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- W2021172849 abstract "Abstract The mixed sulfides MxZn(1−x)S (M = Co, Ni; 0 ≤ x ≤ 0.1) were prepared and their X-ray diffractograms and uv-visible diffuse reflectance spectra were recorded. Hydrogenation of propene over the mixed sulfides was carried out in a static reactor at 480 °C and 345 Torr initial pressure (hydrogen:propene = 1:1). CoS was more active than NiS. Increasing amounts of Co2+ ions in the Co-Zn-S system did not show any significant increase of activity but for the Ni-Zn-S system the activity increased with the Ni2+ ion content from x = 0.0 to 0.1 making the activity of Ni0.1Zn0.9S greater than that of NiS. Cobalt or nickel ions in octahedral coordination by S2− ions are thought to be the active species in the catalytic hydrogenation of propene." @default.
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- W2021172849 date "1982-07-01" @default.
- W2021172849 modified "2023-09-24" @default.
- W2021172849 title "Hydrogenation of propene catalyzed by cobalt and nickel dispersed in zinc sulfide" @default.
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- W2021172849 doi "https://doi.org/10.1016/0021-9517(82)90246-9" @default.
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