FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2021198214> ?p ?o ?g. }

• W2021198214 endingPage "5032" @default.
• W2021198214 startingPage "5021" @default.
• W2021198214 abstract "The products of the reaction of OH with acetone (OH + CH3C(O)CH3 → products) were investigated using a discharge flow tube coupled to a chemical ionization mass spectrometer. It was shown that the yield of acetic acid from the reaction was less than 1% between 237 and 353 K. The yield of acetonyl radical was measured to be (96 ± 11)%, independent of temperature, between 242 and 350 K. The rate coefficients for the reaction were measured with this system to be the same as those reported in part 1 (J. Phys. Chem. A 2003, 107, 5014). The rate coefficients for the removal of OH (v = 1) by acetone and acetone-d6 were shown to be (2.67 ± 0.15) × 10-11 and (3.45 ± 0.24) × 10-11 cm3 molecule-1 s-1, respectively, at 295 K. It was shown that the enthalpy of reaction for the formation of an OH−acetone adduct is more than −8 kcal mol-1 (i.e., the adduct is bound by at most 8 kcal mol-1) at 203 K. On the basis of these observations and those from part 1, we deduce that the reaction of OH with acetone occurs through a hydrogen-bonded complex that gives almost exclusively CH3C(O)CH2 and H2O. The atmospheric implications of our findings are discussed." @default.
• W2021198214 created "2016-06-24" @default.
• W2021198214 creator A5000563547 @default.
• W2021198214 creator A5012123132 @default.
• W2021198214 creator A5049434478 @default.
• W2021198214 creator A5079996955 @default.
• W2021198214 date "2003-06-01" @default.
• W2021198214 modified "2023-10-16" @default.
• W2021198214 title "Reaction of Hydroxyl Radical with Acetone. 2. Products and Reaction Mechanism" @default.
• W2021198214 cites W1819556921 @default.
• W2021198214 cites W1913747830 @default.
• W2021198214 cites W1968202500 @default.
• W2021198214 cites W1975879446 @default.
• W2021198214 cites W1979032281 @default.
• W2021198214 cites W1986762058 @default.
• W2021198214 cites W199153925 @default.
• W2021198214 cites W1995761417 @default.
• W2021198214 cites W1997014635 @default.
• W2021198214 cites W2014064146 @default.
• W2021198214 cites W2033070856 @default.
• W2021198214 cites W2043826713 @default.
• W2021198214 cites W2046750526 @default.
• W2021198214 cites W2056764482 @default.
• W2021198214 cites W2061611910 @default.
• W2021198214 cites W2069892119 @default.
• W2021198214 cites W2073378175 @default.
• W2021198214 cites W2082315410 @default.
• W2021198214 cites W2084627243 @default.
• W2021198214 cites W2084707265 @default.
• W2021198214 cites W2104350809 @default.
• W2021198214 cites W2264878906 @default.
• W2021198214 cites W769518098 @default.
• W2021198214 cites W79645211 @default.
• W2021198214 doi "https://doi.org/10.1021/jp0273023" @default.
• W2021198214 hasPublicationYear "2003" @default.
• W2021198214 type Work @default.
• W2021198214 sameAs 2021198214 @default.
• W2021198214 citedByCount "57" @default.
• W2021198214 countsByYear W20211982142012 @default.
• W2021198214 countsByYear W20211982142015 @default.
• W2021198214 countsByYear W20211982142018 @default.
• W2021198214 countsByYear W20211982142019 @default.
• W2021198214 countsByYear W20211982142021 @default.
• W2021198214 countsByYear W20211982142022 @default.
• W2021198214 countsByYear W20211982142023 @default.
• W2021198214 crossrefType "journal-article" @default.
• W2021198214 hasAuthorship W2021198214A5000563547 @default.
• W2021198214 hasAuthorship W2021198214A5012123132 @default.
• W2021198214 hasAuthorship W2021198214A5049434478 @default.
• W2021198214 hasAuthorship W2021198214A5079996955 @default.
• W2021198214 hasConcept C108204754 @default.
• W2021198214 hasConcept C121332964 @default.
• W2021198214 hasConcept C134121241 @default.
• W2021198214 hasConcept C139066938 @default.
• W2021198214 hasConcept C145148216 @default.
• W2021198214 hasConcept C155647269 @default.
• W2021198214 hasConcept C161790260 @default.
• W2021198214 hasConcept C162356407 @default.
• W2021198214 hasConcept C178790620 @default.
• W2021198214 hasConcept C185592680 @default.
• W2021198214 hasConcept C191897082 @default.
• W2021198214 hasConcept C192562407 @default.
• W2021198214 hasConcept C198291218 @default.
• W2021198214 hasConcept C2776673659 @default.
• W2021198214 hasConcept C2776778087 @default.
• W2021198214 hasConcept C2778581169 @default.
• W2021198214 hasConcept C2781213060 @default.
• W2021198214 hasConcept C3288061 @default.
• W2021198214 hasConcept C32909587 @default.
• W2021198214 hasConcept C43617362 @default.
• W2021198214 hasConcept C51884965 @default.
• W2021198214 hasConcept C62520636 @default.
• W2021198214 hasConcept C65024703 @default.
• W2021198214 hasConcept C75473681 @default.
• W2021198214 hasConceptScore W2021198214C108204754 @default.
• W2021198214 hasConceptScore W2021198214C121332964 @default.
• W2021198214 hasConceptScore W2021198214C134121241 @default.
• W2021198214 hasConceptScore W2021198214C139066938 @default.
• W2021198214 hasConceptScore W2021198214C145148216 @default.
• W2021198214 hasConceptScore W2021198214C155647269 @default.
• W2021198214 hasConceptScore W2021198214C161790260 @default.
• W2021198214 hasConceptScore W2021198214C162356407 @default.
• W2021198214 hasConceptScore W2021198214C178790620 @default.
• W2021198214 hasConceptScore W2021198214C185592680 @default.
• W2021198214 hasConceptScore W2021198214C191897082 @default.
• W2021198214 hasConceptScore W2021198214C192562407 @default.
• W2021198214 hasConceptScore W2021198214C198291218 @default.
• W2021198214 hasConceptScore W2021198214C2776673659 @default.
• W2021198214 hasConceptScore W2021198214C2776778087 @default.
• W2021198214 hasConceptScore W2021198214C2778581169 @default.
• W2021198214 hasConceptScore W2021198214C2781213060 @default.
• W2021198214 hasConceptScore W2021198214C3288061 @default.
• W2021198214 hasConceptScore W2021198214C32909587 @default.
• W2021198214 hasConceptScore W2021198214C43617362 @default.
• W2021198214 hasConceptScore W2021198214C51884965 @default.
• W2021198214 hasConceptScore W2021198214C62520636 @default.
• W2021198214 hasConceptScore W2021198214C65024703 @default.
• W2021198214 hasConceptScore W2021198214C75473681 @default.

• next