Matches in SemOpenAlex for { <https://semopenalex.org/work/W2021221984> ?p ?o ?g. }
Showing items 1 to 74 of
74
with 100 items per page.
- W2021221984 abstract "The new complex catalysts were synthesized by the reaction of titanium compounds (titanium chlorideor titanium butoxide) and diamines in this work, and they showed very high catalytic activities for the cyclododecatriene(CDT) synthesis from 1,3-butadiene through trimerization. CDT synthetic reaction was performed in an autoclavereactor, and the effects of reaction temperature, type of catalyst, catalyst amount added into the system, themole ratio of Al/Ti and immobilization method were investigated on the yield of product CDT. The titanium complexcatalyst combined to diamine with 1:1 ratio showed high selectivity to CDT more than 90%. The ratio of TTT-CDT/TTC-CDT isomers in the product revealed as different values, depending on the type of diamine combined to titaniumand Ti/diamine ratios. Those homogeneous complexes could be used as a heterogenized catalyst after anchoringon the supports, and the immobilized titanium catalyst retained the catalytic activities for several times in therecycled reactions without leaching. The carbon support containing titanium has exhibited superior activity to the silicasupport. Especially, when the titanium complex was anchored on the support which was fabricated by the hydrolysisof tripropylaminosilane itself, the resulting titanium catalyst showed the highest BD conversion and CDTselectivity." @default.
- W2021221984 created "2016-06-24" @default.
- W2021221984 creator A5015685145 @default.
- W2021221984 creator A5080197428 @default.
- W2021221984 creator A5082967768 @default.
- W2021221984 date "2013-06-01" @default.
- W2021221984 modified "2023-09-28" @default.
- W2021221984 title "Synthesis of Cyclododecatriene from 1,3-Butadiene by Trimerization over Amine-Titanium Complex Catalyst" @default.
- W2021221984 cites W1517658931 @default.
- W2021221984 cites W2039437186 @default.
- W2021221984 cites W2056414250 @default.
- W2021221984 cites W2097437825 @default.
- W2021221984 cites W2327060746 @default.
- W2021221984 cites W2228435491 @default.
- W2021221984 cites W2283524988 @default.
- W2021221984 doi "https://doi.org/10.9713/kcer.2013.51.3.394" @default.
- W2021221984 hasPublicationYear "2013" @default.
- W2021221984 type Work @default.
- W2021221984 sameAs 2021221984 @default.
- W2021221984 citedByCount "0" @default.
- W2021221984 crossrefType "journal-article" @default.
- W2021221984 hasAuthorship W2021221984A5015685145 @default.
- W2021221984 hasAuthorship W2021221984A5080197428 @default.
- W2021221984 hasAuthorship W2021221984A5082967768 @default.
- W2021221984 hasBestOaLocation W20212219841 @default.
- W2021221984 hasConcept C118792377 @default.
- W2021221984 hasConcept C13965031 @default.
- W2021221984 hasConcept C161790260 @default.
- W2021221984 hasConcept C178790620 @default.
- W2021221984 hasConcept C179104552 @default.
- W2021221984 hasConcept C185592680 @default.
- W2021221984 hasConcept C188027245 @default.
- W2021221984 hasConcept C192562407 @default.
- W2021221984 hasConcept C2780871995 @default.
- W2021221984 hasConcept C43088074 @default.
- W2021221984 hasConcept C506065880 @default.
- W2021221984 hasConceptScore W2021221984C118792377 @default.
- W2021221984 hasConceptScore W2021221984C13965031 @default.
- W2021221984 hasConceptScore W2021221984C161790260 @default.
- W2021221984 hasConceptScore W2021221984C178790620 @default.
- W2021221984 hasConceptScore W2021221984C179104552 @default.
- W2021221984 hasConceptScore W2021221984C185592680 @default.
- W2021221984 hasConceptScore W2021221984C188027245 @default.
- W2021221984 hasConceptScore W2021221984C192562407 @default.
- W2021221984 hasConceptScore W2021221984C2780871995 @default.
- W2021221984 hasConceptScore W2021221984C43088074 @default.
- W2021221984 hasConceptScore W2021221984C506065880 @default.
- W2021221984 hasLocation W20212219841 @default.
- W2021221984 hasOpenAccess W2021221984 @default.
- W2021221984 hasPrimaryLocation W20212219841 @default.
- W2021221984 hasRelatedWork W1579424930 @default.
- W2021221984 hasRelatedWork W2013505278 @default.
- W2021221984 hasRelatedWork W2039394556 @default.
- W2021221984 hasRelatedWork W2059673851 @default.
- W2021221984 hasRelatedWork W2068581383 @default.
- W2021221984 hasRelatedWork W2084946386 @default.
- W2021221984 hasRelatedWork W2087573492 @default.
- W2021221984 hasRelatedWork W2093149643 @default.
- W2021221984 hasRelatedWork W2150844170 @default.
- W2021221984 hasRelatedWork W2355159592 @default.
- W2021221984 hasRelatedWork W2359061844 @default.
- W2021221984 hasRelatedWork W2367450253 @default.
- W2021221984 hasRelatedWork W2370546012 @default.
- W2021221984 hasRelatedWork W2371694577 @default.
- W2021221984 hasRelatedWork W2380419676 @default.
- W2021221984 hasRelatedWork W2386258385 @default.
- W2021221984 hasRelatedWork W2390720609 @default.
- W2021221984 hasRelatedWork W2392918623 @default.
- W2021221984 hasRelatedWork W2393307446 @default.
- W2021221984 hasRelatedWork W309390145 @default.
- W2021221984 isParatext "false" @default.
- W2021221984 isRetracted "false" @default.
- W2021221984 magId "2021221984" @default.
- W2021221984 workType "article" @default.