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• W2021226964 abstract "Diphosphine palladium(0) (1) and arylpalladium(II) bromide complexes (2a−d) of di-1-adamantyl-n-butylphosphine (CataCXium A) have been synthesized. The PdL2 complex 1 takes a remarkable eclipsed conformation of the substituents along the P−Pd−P direction. NMR and X-ray studies of 2a showed its dimeric structure with the n-butyl groups of the coordinated phosphine ligands lying nearly parallel to the planes of the aromatic rings, which results in an anomalous 1H NMR upfield shift of the n-butyl protons caused by the aromatic ring current effect." @default.
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• W2021226964 date "2008-01-01" @default.
• W2021226964 modified "2023-09-24" @default.
• W2021226964 title "Synthesis and Crystal Structure of Palladium(0) and Arylpalladium(II) Bromide Complexes of Cata<i>CX</i>ium A" @default.
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• W2021226964 doi "https://doi.org/10.1021/om700889b" @default.
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