FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2021244993> ?p ?o ?g. }

• W2021244993 abstract "Abstract The microwave spectrum of ethylphosphonic difluoride, CH3CH2P(O)F2, has been recorded from 26.5 to 39.0 GHz. The R-branches of the a-type transitions have been assigned for both the trans and gauche conformers. For the gauche conformer, the b-type Q transitions of the ground and one vibrationally excited states have also been assigned. Utilizing 91 transitions for the gauche form and 14 transitions for the trans form, the rotational and first order distortional constants have been obtained. From relative intensity measurements, it is estimated that the enthalpy difference between the two conformers is less than 10 cm−1. Ab initio calculations have been carried out using the RHF 3-21 G ∗ , RHF 6-31 G ∗ and MP 2 6-31 G ∗ basis sets, from which structural parameters have been obtained. Utilizing the ab initio data, along with the six rotational constants, structural parameters have been determined by the diagnostic least-squares adjustment procedure. Additionally, from measurements of the frequency of the Stark effect, the dipole moment components of the gauche conformer have been determined. The experimental results are compared to those for some similar molecules." @default.
• W2021244993 created "2016-06-24" @default.
• W2021244993 creator A5029798077 @default.
• W2021244993 creator A5044868665 @default.
• W2021244993 creator A5090150220 @default.
• W2021244993 date "1995-09-01" @default.
• W2021244993 modified "2023-09-27" @default.
• W2021244993 title "Spectra and structure of organophosphorus compounds. LV. Microwave spectrum, structure, and ab initio calculations of ethylphosphonic difluoride" @default.
• W2021244993 cites W1545541503 @default.
• W2021244993 cites W1575142888 @default.
• W2021244993 cites W1625786724 @default.
• W2021244993 cites W1638846815 @default.
• W2021244993 cites W1965224023 @default.
• W2021244993 cites W1966389523 @default.
• W2021244993 cites W1976506014 @default.
• W2021244993 cites W1977088826 @default.
• W2021244993 cites W1987640504 @default.
• W2021244993 cites W1991973831 @default.
• W2021244993 cites W2022464938 @default.
• W2021244993 cites W2023776355 @default.
• W2021244993 cites W2024018745 @default.
• W2021244993 cites W2024354775 @default.
• W2021244993 cites W2030575251 @default.
• W2021244993 cites W2050201458 @default.
• W2021244993 cites W2064440547 @default.
• W2021244993 cites W2066625648 @default.
• W2021244993 cites W2066994597 @default.
• W2021244993 cites W2072138048 @default.
• W2021244993 cites W2079130864 @default.
• W2021244993 cites W2086036207 @default.
• W2021244993 cites W2095015369 @default.
• W2021244993 cites W2115878464 @default.
• W2021244993 cites W248028356 @default.
• W2021244993 cites W2949523832 @default.
• W2021244993 cites W3096378285 @default.
• W2021244993 cites W88291505 @default.
• W2021244993 doi "https://doi.org/10.1016/0022-2860(95)08897-5" @default.
• W2021244993 hasPublicationYear "1995" @default.
• W2021244993 type Work @default.
• W2021244993 sameAs 2021244993 @default.
• W2021244993 citedByCount "4" @default.
• W2021244993 crossrefType "journal-article" @default.
• W2021244993 hasAuthorship W2021244993A5029798077 @default.
• W2021244993 hasAuthorship W2021244993A5044868665 @default.
• W2021244993 hasAuthorship W2021244993A5090150220 @default.
• W2021244993 hasConcept C121332964 @default.
• W2021244993 hasConcept C147597530 @default.
• W2021244993 hasConcept C173523689 @default.
• W2021244993 hasConcept C176166287 @default.
• W2021244993 hasConcept C178790620 @default.
• W2021244993 hasConcept C181500209 @default.
• W2021244993 hasConcept C183971685 @default.
• W2021244993 hasConcept C184779094 @default.
• W2021244993 hasConcept C185592680 @default.
• W2021244993 hasConcept C18705241 @default.
• W2021244993 hasConcept C2781442258 @default.
• W2021244993 hasConcept C31100168 @default.
• W2021244993 hasConcept C3288061 @default.
• W2021244993 hasConcept C32909587 @default.
• W2021244993 hasConcept C97355855 @default.
• W2021244993 hasConceptScore W2021244993C121332964 @default.
• W2021244993 hasConceptScore W2021244993C147597530 @default.
• W2021244993 hasConceptScore W2021244993C173523689 @default.
• W2021244993 hasConceptScore W2021244993C176166287 @default.
• W2021244993 hasConceptScore W2021244993C178790620 @default.
• W2021244993 hasConceptScore W2021244993C181500209 @default.
• W2021244993 hasConceptScore W2021244993C183971685 @default.
• W2021244993 hasConceptScore W2021244993C184779094 @default.
• W2021244993 hasConceptScore W2021244993C185592680 @default.
• W2021244993 hasConceptScore W2021244993C18705241 @default.
• W2021244993 hasConceptScore W2021244993C2781442258 @default.
• W2021244993 hasConceptScore W2021244993C31100168 @default.
• W2021244993 hasConceptScore W2021244993C3288061 @default.
• W2021244993 hasConceptScore W2021244993C32909587 @default.
• W2021244993 hasConceptScore W2021244993C97355855 @default.
• W2021244993 hasLocation W20212449931 @default.
• W2021244993 hasOpenAccess W2021244993 @default.
• W2021244993 hasPrimaryLocation W20212449931 @default.
• W2021244993 hasRelatedWork W1970824338 @default.
• W2021244993 hasRelatedWork W1988252245 @default.
• W2021244993 hasRelatedWork W2002754487 @default.
• W2021244993 hasRelatedWork W2023023876 @default.
• W2021244993 hasRelatedWork W2025411127 @default.
• W2021244993 hasRelatedWork W2025891363 @default.
• W2021244993 hasRelatedWork W2029902361 @default.
• W2021244993 hasRelatedWork W2031263592 @default.
• W2021244993 hasRelatedWork W2037641729 @default.
• W2021244993 hasRelatedWork W2048145163 @default.
• W2021244993 hasRelatedWork W2059320477 @default.
• W2021244993 hasRelatedWork W2070809058 @default.
• W2021244993 hasRelatedWork W2085394751 @default.
• W2021244993 hasRelatedWork W2090509479 @default.
• W2021244993 hasRelatedWork W2094106209 @default.
• W2021244993 hasRelatedWork W2094404316 @default.
• W2021244993 hasRelatedWork W209487914 @default.
• W2021244993 hasRelatedWork W2107343758 @default.
• W2021244993 hasRelatedWork W2146039786 @default.
• W2021244993 hasRelatedWork W236950728 @default.
• W2021244993 isParatext "false" @default.
• W2021244993 isRetracted "false" @default.

• next