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- W2021262017 abstract "Partial oxidation of lactose over Au-based catalyst system using nanostructured silica materials with improved activity, selectivity and stability was investigated as a novel chemo-catalytic approach for selective synthesis of lactobionic acid (LBA) for therapeutic, pharmaceutical and food grad applications. Highly active gold crystallites dispersed on mesoporous silica (SiO2-meso) using bis-[3-(triethoxysilyl) propyl] tetrasulfide (BTSPT), a silane coupling agent to immobilize gold, were successfully formulated, and their catalytic activity was evaluated in an agitated semi-batch reactor. The catalysts were characterized by N2 physisorption, XRD, XPS and TEM. The influence of the reaction conditions, i.e., temperature, pH value, metal loading and catalyst/lactose ratio on lactose conversion were investigated. After 100 min of reaction, the catalyst containing 0.7% Au showed the highest catalytic activity (100% lactose conversion) and a 100% selectivity towards LBA, when it was used at a catalyst/lactose ratio of 0.2 under alkaline (pH 9.0) and mild reaction temperature (65 °C)." @default.
- W2021262017 created "2016-06-24" @default.
- W2021262017 creator A5066320608 @default.
- W2021262017 creator A5067140700 @default.
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- W2021262017 date "2011-07-01" @default.
- W2021262017 modified "2023-09-27" @default.
- W2021262017 title "Selective production of lactobionic acid by aerobic oxidation of lactose over gold crystallites supported on mesoporous silica" @default.
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- W2021262017 doi "https://doi.org/10.1016/j.apcata.2011.05.034" @default.
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