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- W2021265647 abstract "57Fe Mössbauer spectroscopic studies on M(CO)5(azaferrocene) complexes (M = Cr, Mo, W) as well as the crystal structures of W(CO)5(azaferrocene) and W(CO)5(2,5-dimethylazaferrocene) are reported. The complexation of azaferrocene to the M(CO)5 moiety brings about only a small change in the quadrupole splitting. The structures of both tungsten complexes reveal a significant shortening of the W-C bonds trans to the nitrogen. These data indicate that azaferrocene behaves as a relatively strong σ-donor and there is no evidence for any π-acceptor properties." @default.
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- W2021265647 date "1997-08-01" @default.
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- W2021265647 title "57Fe Mössbauer spectroscopic studies on M(CO)5(azaferrocene) complexes (M = Cr, Mo, W). The crystal structures of W(CO)5(azaferrocene) and W(CO)5(2,5-dimethylazaferrocene)" @default.
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- W2021265647 doi "https://doi.org/10.1016/s0022-328x(97)00136-8" @default.
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