Matches in SemOpenAlex for { <https://semopenalex.org/work/W2021276073> ?p ?o ?g. }
- W2021276073 endingPage "420" @default.
- W2021276073 startingPage "409" @default.
- W2021276073 abstract "The possible mechanisms for the chiral recognition of 2(S)-(3,5-bis-trifluoromethyl-phenyl)-2-[3(S)-(4-fluorophenyl)-4-(1H-[1,2,4]triazol-3-ylmethyl)-morpholin-2(R)-yloxy]-ethanol (compound A) and its enantiomer with native γ-cyclodextrin (γ-CD) were investigated using capillary electrophoresis (CE), reversed-phase liquid chromatography (RPLC), proton (1H), fluorine (19F) and carbon (13C) nuclear magnetic resonance spectroscopy (NMR), electrospray mass spectrometry (ESI-MS) and circular dichroism (CD). All experiments provided clear evidence of the formation of diastereomeric complexes between the enantiomers and γ-CD. Proton, fluorine and carbon NMR spectra suggested that both aromatic rings, with mono-fluoro and bis-tri-fluoro functional groups, on the guest molecule were partially included into the cavity of the γ-CD. ESI-MS spectra indicated that the diastereomeric complexes have a 1:1 stoichiometric ratio. The binding constants of the diastereomeric complexes obtained by CE, RPLC and CD were compared. The effects of the γ-CD concentration, organic modifiers and temperature on the CE-chiral separation were also investigated." @default.
- W2021276073 created "2016-06-24" @default.
- W2021276073 creator A5015186372 @default.
- W2021276073 creator A5016568717 @default.
- W2021276073 creator A5024102857 @default.
- W2021276073 creator A5044723261 @default.
- W2021276073 creator A5079366824 @default.
- W2021276073 creator A5081366427 @default.
- W2021276073 creator A5082528423 @default.
- W2021276073 date "2003-02-01" @default.
- W2021276073 modified "2023-10-18" @default.
- W2021276073 title "Mechanistic study of enantiomeric recognition with native γ-cyclodextrin by capillary electrophoresis, reversed-phase liquid chromatography, nuclear magnetic resonance spectroscopy, electrospray mass spectrometry and circular dichroism techniques" @default.
- W2021276073 cites W1490627795 @default.
- W2021276073 cites W1503478950 @default.
- W2021276073 cites W1554220402 @default.
- W2021276073 cites W1965333537 @default.
- W2021276073 cites W1968773465 @default.
- W2021276073 cites W1971790977 @default.
- W2021276073 cites W1977611196 @default.
- W2021276073 cites W1980784006 @default.
- W2021276073 cites W1981297199 @default.
- W2021276073 cites W2005559920 @default.
- W2021276073 cites W2016522356 @default.
- W2021276073 cites W2020709453 @default.
- W2021276073 cites W2026769284 @default.
- W2021276073 cites W2027013654 @default.
- W2021276073 cites W2030205995 @default.
- W2021276073 cites W2038273007 @default.
- W2021276073 cites W2041062106 @default.
- W2021276073 cites W2042466150 @default.
- W2021276073 cites W2046109662 @default.
- W2021276073 cites W2051788521 @default.
- W2021276073 cites W2057910396 @default.
- W2021276073 cites W2058318161 @default.
- W2021276073 cites W2060885878 @default.
- W2021276073 cites W2062617026 @default.
- W2021276073 cites W2065924290 @default.
- W2021276073 cites W2070944269 @default.
- W2021276073 cites W2081353311 @default.
- W2021276073 cites W2081691137 @default.
- W2021276073 cites W2082271129 @default.
- W2021276073 cites W2323491420 @default.
- W2021276073 cites W73780043 @default.
- W2021276073 cites W2062324393 @default.
- W2021276073 doi "https://doi.org/10.1016/s0021-9673(02)01414-0" @default.
- W2021276073 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/12613836" @default.
- W2021276073 hasPublicationYear "2003" @default.
- W2021276073 type Work @default.
- W2021276073 sameAs 2021276073 @default.
- W2021276073 citedByCount "36" @default.
- W2021276073 countsByYear W20212760732013 @default.
- W2021276073 countsByYear W20212760732014 @default.
- W2021276073 countsByYear W20212760732015 @default.
- W2021276073 countsByYear W20212760732016 @default.
- W2021276073 countsByYear W20212760732019 @default.
- W2021276073 countsByYear W20212760732022 @default.
- W2021276073 crossrefType "journal-article" @default.
- W2021276073 hasAuthorship W2021276073A5015186372 @default.
- W2021276073 hasAuthorship W2021276073A5016568717 @default.
- W2021276073 hasAuthorship W2021276073A5024102857 @default.
- W2021276073 hasAuthorship W2021276073A5044723261 @default.
- W2021276073 hasAuthorship W2021276073A5079366824 @default.
- W2021276073 hasAuthorship W2021276073A5081366427 @default.
- W2021276073 hasAuthorship W2021276073A5082528423 @default.
- W2021276073 hasConcept C113196181 @default.
- W2021276073 hasConcept C121332964 @default.
- W2021276073 hasConcept C124668440 @default.
- W2021276073 hasConcept C133571119 @default.
- W2021276073 hasConcept C138716334 @default.
- W2021276073 hasConcept C162356407 @default.
- W2021276073 hasConcept C185592680 @default.
- W2021276073 hasConcept C194451485 @default.
- W2021276073 hasConcept C20621625 @default.
- W2021276073 hasConcept C2779433975 @default.
- W2021276073 hasConcept C2900643 @default.
- W2021276073 hasConcept C40684141 @default.
- W2021276073 hasConcept C43617362 @default.
- W2021276073 hasConcept C486523 @default.
- W2021276073 hasConcept C52703039 @default.
- W2021276073 hasConcept C62520636 @default.
- W2021276073 hasConcept C66974803 @default.
- W2021276073 hasConcept C71240020 @default.
- W2021276073 hasConcept C7602139 @default.
- W2021276073 hasConcept C8010536 @default.
- W2021276073 hasConceptScore W2021276073C113196181 @default.
- W2021276073 hasConceptScore W2021276073C121332964 @default.
- W2021276073 hasConceptScore W2021276073C124668440 @default.
- W2021276073 hasConceptScore W2021276073C133571119 @default.
- W2021276073 hasConceptScore W2021276073C138716334 @default.
- W2021276073 hasConceptScore W2021276073C162356407 @default.
- W2021276073 hasConceptScore W2021276073C185592680 @default.
- W2021276073 hasConceptScore W2021276073C194451485 @default.
- W2021276073 hasConceptScore W2021276073C20621625 @default.
- W2021276073 hasConceptScore W2021276073C2779433975 @default.
- W2021276073 hasConceptScore W2021276073C2900643 @default.
- W2021276073 hasConceptScore W2021276073C40684141 @default.
- W2021276073 hasConceptScore W2021276073C43617362 @default.
- W2021276073 hasConceptScore W2021276073C486523 @default.