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- W2021302503 abstract "Tetrakis complexes of d10 metals with PhP(OR)2 (R = CH3, C2H5) are prepared by reduction of anhydrous metal(II) halides in absolute ROH using an excess ol ligand. The new complexes characterized here are Ni[PhP(OR)2]4, Pd[PhP(OR)2]4, and Cu[PhP(OR)2]4Cl. The Pd10 and CuI complexes are much more air sensitive than the Ni0 complexes, which are relatively stable. The absorption spectrum of each of the complexes shows a band at lower energy than the first system exhibited by the free ligand; assuming approximate tetrahedral stereochemistry, this band is assigned to the metal to ligand transitions d(2e, 3t2) → π*PhP(OR)2." @default.
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- W2021302503 date "1969-01-01" @default.
- W2021302503 modified "2023-09-23" @default.
- W2021302503 title "Synthesis and electronic structures of tetrakis complexes of phenyldialkoxyphophines with d10 metals" @default.
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- W2021302503 doi "https://doi.org/10.1016/s0020-1693(00)92436-8" @default.
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