Matches in SemOpenAlex for { <https://semopenalex.org/work/W2021305037> ?p ?o ?g. }
- W2021305037 abstract "Abstract The cathodic reduction of nine ‘Costa-type’ organocobalt B12 model compounds, [RCo(III)L]C1O4 (where R = alkyl ligand; L = N2,N2′-propanediylbis- (2,3-butanedione 2-imine 3-oxime) and a neutral base), was studied in acetonitrile solvent, using cyclic voltammetry, controlled potential coulometry, and spectroelectrochemical techniques. The effect of the alkyl substituents, namely i-C3H7, neo-C5H11, i-C4H9, CH3CH2, C6H5CH2, CH3, HO(CH2)2, CH3- COOCH2 and CF3CH2, on the relevant cobalt reduction mechanisms and potentials was investigated. A marked infiuence of axial group bulk on the reactivity of the low oxidation state cobalt derivatives formed in the reduction process has been evidentiated. The reactivity of these electrogenerated compounds is conditioned for the most part by their ability to form stable bisalkyl complexes." @default.
- W2021305037 created "2016-06-24" @default.
- W2021305037 creator A5041540065 @default.
- W2021305037 creator A5045024018 @default.
- W2021305037 creator A5068510051 @default.
- W2021305037 creator A5090283346 @default.
- W2021305037 date "1990-02-01" @default.
- W2021305037 modified "2023-09-26" @default.
- W2021305037 title "Electrochemical behavior of ‘costa-type’ organocobalt coenzyme B12 models" @default.
- W2021305037 cites W1968496011 @default.
- W2021305037 cites W1978355604 @default.
- W2021305037 cites W1981954943 @default.
- W2021305037 cites W1983417934 @default.
- W2021305037 cites W1993178021 @default.
- W2021305037 cites W2007679078 @default.
- W2021305037 cites W2032278701 @default.
- W2021305037 cites W2049807213 @default.
- W2021305037 cites W2052388392 @default.
- W2021305037 cites W2053082858 @default.
- W2021305037 cites W2054216950 @default.
- W2021305037 cites W2080870150 @default.
- W2021305037 cites W2083218372 @default.
- W2021305037 cites W2090260860 @default.
- W2021305037 cites W2342438490 @default.
- W2021305037 doi "https://doi.org/10.1016/s0020-1693(00)88027-5" @default.
- W2021305037 hasPublicationYear "1990" @default.
- W2021305037 type Work @default.
- W2021305037 sameAs 2021305037 @default.
- W2021305037 citedByCount "11" @default.
- W2021305037 crossrefType "journal-article" @default.
- W2021305037 hasAuthorship W2021305037A5041540065 @default.
- W2021305037 hasAuthorship W2021305037A5045024018 @default.
- W2021305037 hasAuthorship W2021305037A5068510051 @default.
- W2021305037 hasAuthorship W2021305037A5090283346 @default.
- W2021305037 hasConcept C109379892 @default.
- W2021305037 hasConcept C116569031 @default.
- W2021305037 hasConcept C142724271 @default.
- W2021305037 hasConcept C147789679 @default.
- W2021305037 hasConcept C155647269 @default.
- W2021305037 hasConcept C161790260 @default.
- W2021305037 hasConcept C170493617 @default.
- W2021305037 hasConcept C17525397 @default.
- W2021305037 hasConcept C178790620 @default.
- W2021305037 hasConcept C179104552 @default.
- W2021305037 hasConcept C185592680 @default.
- W2021305037 hasConcept C204787440 @default.
- W2021305037 hasConcept C2776573223 @default.
- W2021305037 hasConcept C2776910235 @default.
- W2021305037 hasConcept C2777463227 @default.
- W2021305037 hasConcept C2777869211 @default.
- W2021305037 hasConcept C2779648554 @default.
- W2021305037 hasConcept C2780263894 @default.
- W2021305037 hasConcept C515602321 @default.
- W2021305037 hasConcept C52859227 @default.
- W2021305037 hasConcept C55493867 @default.
- W2021305037 hasConcept C55904794 @default.
- W2021305037 hasConcept C71240020 @default.
- W2021305037 hasConcept C71924100 @default.
- W2021305037 hasConceptScore W2021305037C109379892 @default.
- W2021305037 hasConceptScore W2021305037C116569031 @default.
- W2021305037 hasConceptScore W2021305037C142724271 @default.
- W2021305037 hasConceptScore W2021305037C147789679 @default.
- W2021305037 hasConceptScore W2021305037C155647269 @default.
- W2021305037 hasConceptScore W2021305037C161790260 @default.
- W2021305037 hasConceptScore W2021305037C170493617 @default.
- W2021305037 hasConceptScore W2021305037C17525397 @default.
- W2021305037 hasConceptScore W2021305037C178790620 @default.
- W2021305037 hasConceptScore W2021305037C179104552 @default.
- W2021305037 hasConceptScore W2021305037C185592680 @default.
- W2021305037 hasConceptScore W2021305037C204787440 @default.
- W2021305037 hasConceptScore W2021305037C2776573223 @default.
- W2021305037 hasConceptScore W2021305037C2776910235 @default.
- W2021305037 hasConceptScore W2021305037C2777463227 @default.
- W2021305037 hasConceptScore W2021305037C2777869211 @default.
- W2021305037 hasConceptScore W2021305037C2779648554 @default.
- W2021305037 hasConceptScore W2021305037C2780263894 @default.
- W2021305037 hasConceptScore W2021305037C515602321 @default.
- W2021305037 hasConceptScore W2021305037C52859227 @default.
- W2021305037 hasConceptScore W2021305037C55493867 @default.
- W2021305037 hasConceptScore W2021305037C55904794 @default.
- W2021305037 hasConceptScore W2021305037C71240020 @default.
- W2021305037 hasConceptScore W2021305037C71924100 @default.
- W2021305037 hasLocation W20213050371 @default.
- W2021305037 hasOpenAccess W2021305037 @default.
- W2021305037 hasPrimaryLocation W20213050371 @default.
- W2021305037 hasRelatedWork W1967675512 @default.
- W2021305037 hasRelatedWork W1980970752 @default.
- W2021305037 hasRelatedWork W1982102023 @default.
- W2021305037 hasRelatedWork W1984781132 @default.
- W2021305037 hasRelatedWork W1991569009 @default.
- W2021305037 hasRelatedWork W2004168004 @default.
- W2021305037 hasRelatedWork W2006702840 @default.
- W2021305037 hasRelatedWork W2006815154 @default.
- W2021305037 hasRelatedWork W2007065513 @default.
- W2021305037 hasRelatedWork W2007402881 @default.
- W2021305037 hasRelatedWork W2051853004 @default.
- W2021305037 hasRelatedWork W2056835576 @default.
- W2021305037 hasRelatedWork W2061766221 @default.
- W2021305037 hasRelatedWork W2061950604 @default.
- W2021305037 hasRelatedWork W2065261065 @default.