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- W2021305608 abstract "Graphite will react with both reductants and oxidants to form intercalation compounds which are chemically analogous to ions of aromatic molecules. Specifically, many fluorine-containing molecules will oxidize graphite to make new compounds, and fluorine nuclear magnetic resonance has proved useful in characterizing such products with respect to oxidation state and mobility of the inserted species. Non-oxidizing fluorides (as BF3 or PF5) can be introduced into graphite only with an oxidant (as ClF) to yield highly mobile anions and/or anion-neutral mixtures within the graphite planes. The weakly oxidizing fluoride AsF5 directly intercalates graphite to yield a composite AsF5/AsF3/AsF6− inserted product, which exhibits high molecular mobility within the planes. Strong oxidants as KrF2, XeF6, and IF7 intercalate graphite with correlative formation of covalent CF bonds. In cases in which molecular fluorine is used, either alone (at 24°C, as done by H. Selig) or with a non-oxidizer as WF6, one observes a symmetric electron spin resonance signal whose area obeys the Curie-Weiss Law. This behavior, which is in contrast to that found for the graphite/AsF5 product, suggests that fluorine gas will have a deleterious effect on the electronic conductivity of graphite." @default.
- W2021305608 created "2016-06-24" @default.
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- W2021305608 date "1983-11-01" @default.
- W2021305608 modified "2023-09-23" @default.
- W2021305608 title "Magnetic resonance of fluorine-containing intercalation compounds of graphite" @default.
- W2021305608 doi "https://doi.org/10.1016/s0022-1139(00)85498-6" @default.
- W2021305608 hasPublicationYear "1983" @default.
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