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- W2021307790 abstract "Abstract A monosubstituted polyacetylene having amine functional groups was prepared via the polymerization of 3-ethynylaniline by using transition metal catalysts. The polymerization proceeded well in homogeneous manner to give a relatively high yield of polymer. The polymer structure was characterized by such instrumental methods as IR, NMR, and UV-visible spectroscopies to have the conjugated backbone system with the designed functional groups. The absorption spectrum starts around 700 nm, which is due to the π→ π* interband transition of conjugated polymer system. This polymer exhibited the irreversible electrochemical behaviors between the doping and undoping peaks. Keywords: 3-ethynylanilinecharacterizationconjugated polymerpolyacetylenetransition metal catalyst Acknowledgement This work was supported by the research fund of Kyungil University, ACT-RIC from Regional Innovation Center Program and the Regional Technology Innovation Program (RTI04–01-04) of the Ministry of Knowledge Economy (MKE). The authors thank Ms S. E. Chai of Korea Basic Science Institute-Taegu Branch for the measurement of the 500-MHz FT-NMR spectra of the polymers." @default.
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- W2021307790 date "2012-12-03" @default.
- W2021307790 modified "2023-09-26" @default.
- W2021307790 title "Synthesis and Characterization of a Polyacetylene Derivative Containing Amine Functional Groups" @default.
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- W2021307790 doi "https://doi.org/10.1080/15421406.2012.708844" @default.
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