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• W2021330995 abstract "(4,4′-H2bipy)[HgBr4] · H2O (1), has been synthesized via hydrothermal reaction. The title compound features an isolated structure, based on discrete 4,4′-H2bipy moieties, lattice water molecules and tetrahedral mercury atoms terminally coordinated by four bromine atoms. The 4,4′-H2bipy moieties, lattice water molecules and tetrabromo-mercury dianions are linked via hydrogen bonds. Optical absorption spectrum reveals that the presence of an optical gap of 2.53 eV, indicating that compound 1 exhibits a semiconductor property. Photoluminescent investigation reveals that the title compound displays a strong blue-light emission, which maybe originates from π → π∗ charge-transfer interaction of 4,4′-H2bipy. IR, SEM/EDS and thermogravimetry-differential thermal analyses (TG-DTA) are also presented." @default.
• W2021330995 created "2016-06-24" @default.
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• W2021330995 date "2007-02-01" @default.
• W2021330995 modified "2023-10-18" @default.
• W2021330995 title "Synthesis, structure and properties of (4,4′-H2bipy)[HgBr4]·H2O with strong fluorescence" @default.
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• W2021330995 doi "https://doi.org/10.1016/j.inoche.2006.10.029" @default.
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