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- W2021413710 abstract "The iridium complex-catalyzed asymmetric hydrogenation of quinolines in a DMPEG/hexane biphasic system was studied. Catalysts with C2-symmetric ligands such as Xyl-P-Phos, Cl–MeO–BIPHEP, SYNPHOS, and DifluorPhos are highly effective for this type of reaction. Most of the catalysts tested can be retained in DMPEG (Mn = 500), and the asymmetric hydrogenation of various quinoline substrates can be carried out in DMPEG/hexane biphasic system with up to 92% ee. The catalysts and the products can be separated via simple phase separation, and the reactivity/stereoselectivity of the catalysts can be retained for at least three reaction cycles." @default.
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- W2021413710 date "2007-11-01" @default.
- W2021413710 modified "2023-09-23" @default.
- W2021413710 title "Asymmetric hydrogenation of quinolines with recyclable and air-stable iridium catalyst systems" @default.
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- W2021413710 doi "https://doi.org/10.1016/j.tetasy.2007.10.034" @default.
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