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- W2021420148 abstract "Electron spin resonance spectra of solutions used to make conductive bilayer lipid membranes reveal that free radical formation is a precursor to membrane conductivity. Tetracyanoquinodimethane (TCNQ) forms a stable radical that self-aggregates in nonaqueous media, yet will diffuse into the aqueous phase as a monomer, potentially allowing interfacial exchange. Tetracyanoethylene (TCNE) will undergo hydrolysis via a radical intermediate, and the decomposition product is ESR silent. The electrochemical response of an electrochemical cell partitioned by a membrane modified by these dopants is ionic for TCNE. Although the mechanism is less clear for TCNQ, the role of a stable radical is clearly implicated." @default.
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- W2021420148 title "Free Radical Formation in Reactions of Lecithin with Tetracyanoquinodimethane and Tetracyanoethylene: Relating the Behavior of Membrane-Partitioned Electrochemical Cells to Charge Carrier Using Electron Spin Resonance" @default.
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- W2021420148 doi "https://doi.org/10.1006/abio.1997.2384" @default.
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