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- W2021434771 abstract "Rotationally resolved spectrum of 12CH313CH3 in the region of ν5 vibrational fundamental (CC stretch) was observed using stimulated Raman spectroscopy. This spectrum was analyzed with data from the ν12 fundamental and transitions from the ν6, 2ν6–ν6, and 3ν6 torsional bands using a 3-state fit. One torsional component of the ν5 fundamental is perturbed, interacting with its partner in the ν6=4 of the torsional stack of the ground vibrational state. As for normal ethane, the coupling was successfully modeled using a Fermi-type interaction. The results mirror that of 12CH312CH3 in that the inclusion of the Fermi-type interaction reduces the required number of terms in the Fourier expansion of the torsional potential for the ground vibrational state from three (in the 2-state fit) to one, only the term in the barrier height is required." @default.
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- W2021434771 date "2011-10-01" @default.
- W2021434771 modified "2023-09-28" @default.
- W2021434771 title "The ν5 band of 12CH313CH3: High resolution stimulated Raman spectrum and global three band analysis" @default.
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- W2021434771 doi "https://doi.org/10.1016/j.jms.2011.06.003" @default.
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