FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2021443329> ?p ?o ?g. }

• W2021443329 endingPage "125" @default.
• W2021443329 startingPage "121" @default.
• W2021443329 abstract "Experimental 1H chemical shift analysis for the camphor-based chiral γ-amino alcohol 2 shows a difference of 0.9 ppm for the two diastereotopic hydrogens H11a and H11b. In contrast, for the exo adduct (1) and its acetate (3) these hydrogens have very similar chemical shifts. DFT calculations followed by NBO analysis show that these differences in chemical shifts arise as a consequence of an intramolecular hydrogen bond OH⋯N in 2, which restricts its conformational mobility. In the most stable conformer of 2, the interaction of the nitrogen lone-pair with the vicinal σ*(CH11a) antibonding orbital shifts that hydrogen downfield by 0.9 ppm. This is confirmed by experimental NMR studies based on NULL." @default.
• W2021443329 created "2016-06-24" @default.
• W2021443329 creator A5012760924 @default.
• W2021443329 creator A5031979218 @default.
• W2021443329 creator A5033985755 @default.
• W2021443329 creator A5056067873 @default.
• W2021443329 creator A5076757491 @default.
• W2021443329 date "2007-02-01" @default.
• W2021443329 modified "2023-09-23" @default.
• W2021443329 title "Conformational characterization of a camphor-based chiral γ-amino alcohol" @default.
• W2021443329 cites W1977264880 @default.
• W2021443329 cites W1985593573 @default.
• W2021443329 cites W1990399542 @default.
• W2021443329 cites W1991248359 @default.
• W2021443329 cites W2013053011 @default.
• W2021443329 cites W2019772301 @default.
• W2021443329 cites W2023271753 @default.
• W2021443329 cites W2038533471 @default.
• W2021443329 cites W2051197982 @default.
• W2021443329 cites W2054164390 @default.
• W2021443329 cites W2054376935 @default.
• W2021443329 cites W2057044944 @default.
• W2021443329 cites W2087500654 @default.
• W2021443329 cites W2116540028 @default.
• W2021443329 cites W2130348210 @default.
• W2021443329 cites W2132784344 @default.
• W2021443329 cites W2132795750 @default.
• W2021443329 cites W2143981217 @default.
• W2021443329 cites W2151193855 @default.
• W2021443329 cites W2156115804 @default.
• W2021443329 cites W2950240546 @default.
• W2021443329 cites W2951513661 @default.
• W2021443329 cites W2952202396 @default.
• W2021443329 cites W2952520291 @default.
• W2021443329 cites W2952894987 @default.
• W2021443329 doi "https://doi.org/10.1016/j.molstruc.2006.05.023" @default.
• W2021443329 hasPublicationYear "2007" @default.
• W2021443329 type Work @default.
• W2021443329 sameAs 2021443329 @default.
• W2021443329 citedByCount "3" @default.
• W2021443329 countsByYear W20214433292021 @default.
• W2021443329 crossrefType "journal-article" @default.
• W2021443329 hasAuthorship W2021443329A5012760924 @default.
• W2021443329 hasAuthorship W2021443329A5031979218 @default.
• W2021443329 hasAuthorship W2021443329A5033985755 @default.
• W2021443329 hasAuthorship W2021443329A5056067873 @default.
• W2021443329 hasAuthorship W2021443329A5076757491 @default.
• W2021443329 hasConcept C108204754 @default.
• W2021443329 hasConcept C111429119 @default.
• W2021443329 hasConcept C112887158 @default.
• W2021443329 hasConcept C121332964 @default.
• W2021443329 hasConcept C121349320 @default.
• W2021443329 hasConcept C130188946 @default.
• W2021443329 hasConcept C147120987 @default.
• W2021443329 hasConcept C147597530 @default.
• W2021443329 hasConcept C147789679 @default.
• W2021443329 hasConcept C152365726 @default.
• W2021443329 hasConcept C178790620 @default.
• W2021443329 hasConcept C185592680 @default.
• W2021443329 hasConcept C18705241 @default.
• W2021443329 hasConcept C189394030 @default.
• W2021443329 hasConcept C2780697445 @default.
• W2021443329 hasConcept C2781066024 @default.
• W2021443329 hasConcept C32909587 @default.
• W2021443329 hasConcept C46000676 @default.
• W2021443329 hasConcept C62520636 @default.
• W2021443329 hasConcept C71240020 @default.
• W2021443329 hasConcept C75079739 @default.
• W2021443329 hasConcept C95269574 @default.
• W2021443329 hasConceptScore W2021443329C108204754 @default.
• W2021443329 hasConceptScore W2021443329C111429119 @default.
• W2021443329 hasConceptScore W2021443329C112887158 @default.
• W2021443329 hasConceptScore W2021443329C121332964 @default.
• W2021443329 hasConceptScore W2021443329C121349320 @default.
• W2021443329 hasConceptScore W2021443329C130188946 @default.
• W2021443329 hasConceptScore W2021443329C147120987 @default.
• W2021443329 hasConceptScore W2021443329C147597530 @default.
• W2021443329 hasConceptScore W2021443329C147789679 @default.
• W2021443329 hasConceptScore W2021443329C152365726 @default.
• W2021443329 hasConceptScore W2021443329C178790620 @default.
• W2021443329 hasConceptScore W2021443329C185592680 @default.
• W2021443329 hasConceptScore W2021443329C18705241 @default.
• W2021443329 hasConceptScore W2021443329C189394030 @default.
• W2021443329 hasConceptScore W2021443329C2780697445 @default.
• W2021443329 hasConceptScore W2021443329C2781066024 @default.
• W2021443329 hasConceptScore W2021443329C32909587 @default.
• W2021443329 hasConceptScore W2021443329C46000676 @default.
• W2021443329 hasConceptScore W2021443329C62520636 @default.
• W2021443329 hasConceptScore W2021443329C71240020 @default.
• W2021443329 hasConceptScore W2021443329C75079739 @default.
• W2021443329 hasConceptScore W2021443329C95269574 @default.
• W2021443329 hasIssue "1-3" @default.
• W2021443329 hasLocation W20214433291 @default.
• W2021443329 hasOpenAccess W2021443329 @default.
• W2021443329 hasPrimaryLocation W20214433291 @default.
• W2021443329 hasRelatedWork W1983844696 @default.
• W2021443329 hasRelatedWork W2006174085 @default.
• W2021443329 hasRelatedWork W2010191713 @default.

• next