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- W2021460952 abstract "A detailed account of the development of a recently developed, nickel-catalyzed multicomponent coupling of chiral allenes, aromatic aldehydes, and silanes is described. The axial chirality of the allene is transferred completely to the product, a trisubstituted Z-allylic alcohol protected as a silyl ether. A very high preference for sp rather than sp2 coupling is observed, and differentially substituted allenes undergo highly site-selective coupling. These transformations represent the first enantioselective multi-component coupling processes of allenes." @default.
- W2021460952 created "2016-06-24" @default.
- W2021460952 creator A5044333811 @default.
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- W2021460952 date "2005-11-01" @default.
- W2021460952 modified "2023-09-26" @default.
- W2021460952 title "Enantioselective and regioselective nickel-catalyzed multicomponent coupling of chiral allenes, aromatic aldehydes, and silanes" @default.
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- W2021460952 doi "https://doi.org/10.1016/j.tet.2005.08.063" @default.
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