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- W2021469524 abstract "The reaction of two molar equivalents of the alkyl-substituted (E)-4-lithio-1,4-diazabut-1-ene, Li[μ-N(t-Bu)CH(t-Bu)CHN-t-Bu], with zinc dichloride, cadmium dibromide, or mercury dibromide in diethyl ether yields zinc M{[μ-N(t-Bu)CH(t-Bu)CHN-t-Bu][N(t-Bu)CH(t-Bu)CHN-t-Bu]}, [M=Zn (1)], cadmium M[μ-N(t-Bu)CH(t-Bu)CHN-t-Bu]2, [M=Cd (2)], or mercury M{[μ-N(t-Bu)CH(t-Bu)CHN-t-Bu][N(t-Bu)CH(t-Bu)CHN-t-Bu]} [M=Hg (3)], respectively, as colorless crystals. In the solid state, the central metal of 2 possesses a coordination number of four; compounds 1 and 3 display the rather unusual coordination number of three." @default.
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- W2021469524 date "2001-04-01" @default.
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- W2021469524 title "Synthesis, structural characterization and dynamic behavior of Group 12 metals containing the sterically hindered ligand [N(t-Bu)CH(t-Bu)CHN-t-Bu]−" @default.
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- W2021469524 doi "https://doi.org/10.1016/s0277-5387(01)00697-0" @default.
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