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• W2021506535 abstract "The photodissociation of jet-cooled vibrationally excited CH3Cl near 235 nm has been investigated by detection of the Cl(2P3/2) and Cl(2P1/2) photofragments through resonance enhanced multiphoton ionization (REMPI) in a time-of-flight mass spectrometer. Vibrationally excited molecules with three or four quanta of CH stretch excitation were prepared by irradiation with tunable near infrared (NIR) laser radiation, and a single UV laser beam was used for both photolysis and fragment detection. The action spectra of the photofragments were much more highly resolved than the room-temperature photoacoustic (PA) spectrum. The differing intensities of vibrational bands in the PA and action spectra are discussed." @default.
• W2021506535 created "2016-06-24" @default.
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• W2021506535 date "2001-12-01" @default.
• W2021506535 modified "2023-09-23" @default.
• W2021506535 title "Vibrationally mediated photodissociation of CH3Cl: the v=3 and 4 CH stretch overtone levels" @default.
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• W2021506535 doi "https://doi.org/10.1016/s0009-2614(01)01263-5" @default.
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