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• W2021507444 abstract "The synthesis of important intermediates for tetrodotoxin has been explored. The chiral cyclohexane ring was constructed by electrocyclization from a triene precursor and by conversion to the highly oxygenated cyclohexane ring. In particular, the introduction of an α-hydroxy group at the 5 position (toxin-numbering) in tetrodotoxin was achieved by allylic oxidation with SeO2." @default.
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• W2021507444 date "1998-06-01" @default.
• W2021507444 modified "2023-10-10" @default.
• W2021507444 title "Stereoelectronic and steric control in chiral cyclohexane synthesis toward (−)-tetrodotoxin" @default.
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• W2021507444 doi "https://doi.org/10.1016/s0040-4020(98)00331-7" @default.
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