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• W2021509754 abstract "The 13C, 1H spin-spin coupling constants have been determined for π-benzenechromium tricarbonyl (3) and the π-tropyliumchromium tricarbonyl cation using the 13C{2H}double resonance technique described in a previous paper. In addition, conventional analysis of the 1H-coupled 13C NMR spectrum of 3 was carried out and the 1H NMR spectrum of 3 partially oriented in the nematic phase was analysed. Both treatments also allowed the determination of the 1H, 1H coupling constants for this compound. The nJ(CH) results are discussed on the basis of structural data and the theoretical results available. The complexation effects for 1J(CH) are found to correlate with the CH overlap population and hybridization changes, and those for 3J(CH) with the CC bond lengths and π-bond orders. The dependence of 2J(CH) on CC bond length as well as on the CCH bond angle is indicated. The liquid crystal results are compared with those of related studies." @default.
• W2021509754 created "2016-06-24" @default.
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• W2021509754 date "1980-03-01" @default.
• W2021509754 modified "2023-10-12" @default.
• W2021509754 title "Carbon-13,1H spin-spin coupling. V—π-benzenechromium tricarbonyl and the π-tropyliumchromium tricarbonyl cation" @default.
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• W2021509754 doi "https://doi.org/10.1002/mrc.1270130311" @default.
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