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- W2021520509 abstract "[reaction: see text] All of the crystalline o-anisaldehyde derivatives 1 and 3 change to brick-red color upon brief exposure to UV-vis radiation. The red color, attributed to (E)-xylylenol, is remarkably persistent for hours (ca. 10 h) in the case of 1c; such a long lifetime for the reactive o-xylylenols is unprecedented. In contrast, the p-anisaldehydes 2 undergo cyclization. Solid-state photolysis of 2b affords the benzocyclobutenol 7b regioselectively, which is not accessible from solution-phase photolysis." @default.
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- W2021520509 date "2001-04-13" @default.
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- W2021520509 title "Solid-State Photochromism and Photoreactivity of <i>o</i>- and <i>p</i>-Anisaldehydes. Remarkable Stabilization of <i>o</i>-Xylylenols" @default.
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- W2021520509 doi "https://doi.org/10.1021/ol0158720" @default.
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