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• W2021522511 abstract "An FT-IR spectroscopic study concerning changes in the conformation of sugar in the dinucleotides; GpC and CpG, on platination and intercalation is presented. The results are compared with the FT-IR spectral data of 5′-CMP, 5′-GMP, 3′-GMP and their metal adducts. The spectra of free GpC, free CpG, proflavine-GpC, proflavine-CpG, and cis-[Pt(NH3)2(GpC)2]2+ exhibit the diagnostic band at 800 cm−1 which was assigned to a sugar phosphate vibrational mode and diagnostic of C3′-endo sugar pucker. In the case of 9-aminoacridine-GpC and cis-[Pt(NH3)2(CpG]+ the diagnostic bands of the C2′-endo and C3′-endo conformations are observed at 810–820 cm−1 and near 800 cm−1 respectively. The results are in good agreement with X-ray data. The infrared diagnostic bands are important for distinguishing the sugar pucker conformational changes." @default.
• W2021522511 created "2016-06-24" @default.
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• W2021522511 date "1987-03-01" @default.
• W2021522511 modified "2023-10-13" @default.
• W2021522511 title "FT-IR spectroscopic evidence of sugar ring conformational changes in GpC and CpG on platination and intercalation" @default.
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• W2021522511 doi "https://doi.org/10.1016/s0020-1693(00)81300-6" @default.
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