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- W2021532007 abstract "Collisions of HCl (j = 0) with rare gas and molecular colliders were studied using velocity-mapped ion imaging. For the rare gas colliders, Ne and Kr, the observed scattering behavior is very similar to that previously observed for HCl + Ar, and any differences are primarily due to the rule of corresponding states. For the molecular colliders, N2 and CH4, very different scattering behavior was observed, especially for high ΔjHCl transitions. When HCl is scattered into jHCl = 2 or 3, the collision results in more forward-scattering than is observed for rare gas colliders, whereas when HCl is scattered into jHCl = 4 or 5, the collision results in more backscattering. This implies that to generate HCl in a highly rotationally excited quantum state following collision with a diatomic or polyatomic collider, the collision must have a smaller impact parameter than would be required for an atomic collision." @default.
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- W2021532007 date "2003-05-30" @default.
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- W2021532007 title "Collisions of HCl with Rare Gas and Molecular Colliders" @default.
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- W2021532007 doi "https://doi.org/10.1021/jp027601s" @default.
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