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• W2021535838 abstract "In this study, single-crystal Pd nanocubes and nanooctahedrons were prepared by the colloidal method and their catalytic activities were compared in direct hydrogen peroxide synthesis. Using sodium tetrachloropalladate (II) as the Pd precursor, l-ascorbic acid (or formaldehyde) as the reducing agent, potassium bromide as the capping agent, and polyvinylpyrrolidone as the stabilizer, Pd nanocubes were obtained in a uniform size (9 nm). Pd octahedrons (23 nm in edge length) were synthesized via seed-mediated growth of the Pd nanocube, where the morphology of the cube was altered to that of a cuboctahedron, truncated octahedron, and octahedron, in series. The cubes and octahedrons were enclosed by {1 0 0} and {1 1 1} facets, respectively. In activity tests, the Pd octahedron presented higher hydrogen peroxide selectivity and productivity than the Pd cube. It is therefore suggested that the Pd {1 1 1} facet is more active than the Pd {1 0 0} facet in direct hydrogen peroxide synthesis." @default.
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• W2021535838 date "2014-09-01" @default.
• W2021535838 modified "2023-10-06" @default.
• W2021535838 title "Shape-dependent catalytic activity of palladium nanoparticles for the direct synthesis of hydrogen peroxide from hydrogen and oxygen" @default.
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• W2021535838 doi "https://doi.org/10.1016/j.molcata.2014.03.026" @default.
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