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- W2021551901 abstract "The 2-pivaloyl-1,4-benzoquinone radical anion has been prepared both by electrochemical reduction (in dimethylformamide) and by alkali-metal reduction (in tetrahydrofuran). The e.s.r. spectrum observed in dimethylformamide is that of a single species. However, in tetrahydrofuran the nature of the spectra depend on the alkali-metal counter-ion. For example, linewidth variation is observed when K+ is the counter-ion whilst two separate species are observed when Li+ is the counter-ion. The results of these experiments indicate that the various species result from different locations of the alkalimetal counter-ion adjacent to the radical anion rather than from rotational conformers resulting from the rotation of the pivaloyl group." @default.
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- W2021551901 date "1989-01-01" @default.
- W2021551901 modified "2023-09-26" @default.
- W2021551901 title "An electron spin resonance investigation of the 2-pivaloyl-1,4-benzoquinone radical anion" @default.
- W2021551901 doi "https://doi.org/10.1039/p29890000097" @default.
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