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- W2021555013 abstract "Abstract Two routes to terrein (1), employing a novel ring contraction of 6-alkoxy-2,3-dihydro-6H-pyran-3-ones (5, 13) are described. Separation into enantiomers was carried out by classical resolution via diastereomeric camphanic acid ester intermediates (14, 15). A new method for cleavage of the 2-(trimethylsilyl)ethyl protecting group in the presence of acid and base sensitive functionality is reported." @default.
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- W2021555013 date "1990-01-01" @default.
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- W2021555013 title "A total synthesis of racemic and optically active terrein (trans-4,5-dihydroxy-3-[(E)-1-propenyl]-2-cyclopenten-1-one)." @default.
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- W2021555013 doi "https://doi.org/10.1016/s0957-4166(00)86329-6" @default.
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