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- W2021569183 abstract "Abstract The photochemical reactions of [Ru 3 (CO) 12 ] with the diphosphorus ligands Me 2 PCH 2 PME 2 , Ph 2 PCH 2 PPh 2 and Ph 2 PN(Et)PPh 2 have been found to give tri-, di- or mono-nuclear products, depending on the reaction conditions and the ligand involved. Products isolated include [Ru 3 (CO) 10 [μ-R 2 PYPR 2 ] (Y = CH 2 , R = Me or Ph; Y = N(Et), R = Ph), [Ru 3 (CO) 8 [μ-R 2 PYPR 2 ] 2 ] (Y = CH 2 , R = Me or Ph), [Ru 3 (CO) 6 [μ-R 2 PYPR 2 ] 3 ] (Y = CH 2 , R = Me or Ph), [Ru 2 (μ-CO)(CO) 4 [μ-Ph 2 PCH 2 PPh 2 ] 2 ] and [Ru(CO) 3 [Ph 2 PN(Et)PPh 2 ]. An X-ray crystallographic study has revealed that the diphosphazane ligand in [Ru 3 (CO) 10 [η-Ph 2 PN(Et)PPh 2 ] is coordinated equatorially and that the Ru-Ru edge which it bridges is ca. 0.06 A shorter than the average of the other two edges." @default.
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- W2021569183 date "1988-07-01" @default.
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- W2021569183 title "Reaction of triruthenium dodecacarbonyl with bis(dimethylphosphino)methane, bis(diphenylphosphino)methane and bis(diphenylphosphino)-ethylamine under photochemical conditions" @default.
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- W2021569183 doi "https://doi.org/10.1016/0022-328x(88)87032-3" @default.
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