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- W2021574114 abstract "In alkaline solutions, the 3-deoxyaldosuloses are degraded by two distinct reaction pathways: (1), rearrangements to isomeric saccharinic acids, and (2) to aldonic acids by an oxidative carbon—carbon bond cleavage. Thus, 3-deoxy-d-erythro-hexosulose gave 3-deoxy-d-ribo and d-arabino-hexonic (“α”- and “β”-d-glucometasaccharinic) acids in a ratio of approximately 1 to 4 by a benzyl—benzilic acid type of rearrangement and was oxidized to 2-deoxy-d-erythro-pentonic acid. Similarly, 3-deoxy-d-threo-hexosulose was rearranged to 3-deoxy-d-xylo and d-lyxo-hexonic (“α”- and “β”-d-galactometasaccharinic) acids in the same ratio and was oxidized to 2-deoxy-d-threo-pentonic acid. The preponderant pathway, even under oxidative conditions, was found to be the rearrangement reaction. The effects of cation, alkali concentration, and temperature were also determined." @default.
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- W2021574114 title "Oxidative, alkaline degradation of 3-deoxyaldosuloses" @default.
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