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- W2021575988 abstract "Synthesis conditions for an MTF-type zeolite UTM-1 have been studied and this material has been characterized in detail. UTM-1 is crystallized in the presence of hexamethyleneimine (HMI) under the synthesis conditions similar to those of MCM-22 but from mother gels with high SiO2/Al2O3 ratio at a narrow range of synthesis temperatures. The crystal growth of UTM-1 proceeds quite rapidly after a long induction period in contrast to the gradual crystal growth of MCM-22. Through the optimization of synthesis conditions, pure silica and Ti-incorporated materials with the MTF structure can be easily synthesized in the hydroxide media without employing any co-template other than HMI. UTM-1 is proved to have strong acidity comparable to that of ZSM-5 having a similar SiO2/Al2O3 ratio, presumably reflecting their structural similarity. UTM-1 has large outer surface area so as to show high catalytic activities in reactions occurring at the outer surface of the catalyst, whereas its small pore aperture restricts the diffusivity of reactant molecules into the pore system." @default.
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- W2021575988 date "2002-08-01" @default.
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- W2021575988 title "Synthesis, characterization, and catalysis of UTM-1: an MTF-type zeolite composed of the same building unit as MFI-type zeolites" @default.
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- W2021575988 doi "https://doi.org/10.1016/s1387-1811(02)00408-0" @default.
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