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- W2021583868 abstract "The polarographic reduction of 5,6,11,12-naphthacenetetrone (NT) and several of its chloromethyl, and nitro derivatives were investigated. The electrochemical behavior of NT was compared with 6, 11-dihydroxy-5, 12-naphthacencequinone (DHNQ) previously studied. Like DHNQ, NT exhibits two reduction waves in N,N-dimethylformamide. However, two additional post adsorption waves which were not present in DHNQ reduction were also observed. The first step reduction of NT, representing the formation of the radical anion NT−, has a potential (0.01 V vs sce) much more anodic than that of its DHNQ counterpart ( −0.75 V vs sce). The substituent effects of NTs were noted. A linear Hammett relationship similar to that of the DHNQ series was also found for the NTs. In both cases, the averaged values of σmeta and σpara were used as the substituent constants" @default.
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- W2021583868 date "1982-05-01" @default.
- W2021583868 modified "2023-09-23" @default.
- W2021583868 title "The effects of substitution on the electrochemical reduction of naphthacenetetrone in N,N-Dimethylformamide" @default.
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- W2021583868 doi "https://doi.org/10.1016/0013-4686(82)85047-0" @default.
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