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- W2021594312 abstract "Light scattering studies of the depolarized Rayleigh line are reported for liquid benzene over the temperature range +13 to 76°C and for other substituted benzenes. Values of the 〈 P2(o)P2(t)〉 and 〈 Ṗ2(o)Ṗ2(t)〉 correlation functions calculated from these spectra show considerable free rotor behavior (∼ 15° steps) and incomplete loss of memory after collision. Further consideration of the 〈 Ṗ2(o)Ṗ2(t)〉 correlation allows calculation of the angular velocity correlation function. The time between collisions, τBC, is also obtained and found to be in good agreement with a ``moveable wall'' cell model. It is proposed that the ``shoulder'' noted in the wings of many anisotropic liquids is caused by incomplete loss of memory after collision." @default.
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- W2021594312 date "1973-10-15" @default.
- W2021594312 modified "2023-10-14" @default.
- W2021594312 title "Rayleigh scattering: Orientational motion in highly anisotropic liquids" @default.
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- W2021594312 doi "https://doi.org/10.1063/1.1680649" @default.
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