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- W2021599578 abstract "Three diastereomeric palladium(II) complex cations containing the orthometalated (S)-dimethyl(1-(α-naphthyl)ethyl)amine together with the (R,R)-, (S,S)- and (R,S)- forms of N,N,N',N'-tetramethyl-2,3-butanediamine have been prepared separately as their pcrchlorate salts. The (S,R,R) isomer with [α] D +167 o (c 1.0, CH 2 Cl 2 ) crystallixes in the space group P2 1 2 1 2 1 with a=7.872 (3) A, b=15.843 (5) A, c=20.273 (6) A, Z=4, and R=0.0372.The square-planar geometry around palladium is slightly distorted. The (S,S,S) isomer with [α] D +87 o (c 1.0, CH 2 Cl 2 ) crystallizes in the spaces group P2 1 , with a=7.978 (2) A, b=20.856 (2) A, c=15.218 (2) A, β=90.06 (2) o , Z=4 and R=0.0362" @default.
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- W2021599578 date "1994-07-01" @default.
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- W2021599578 title "Stereochemical Investigation of Bis(bidentate)-Palladium(II) Complexes. Transmission of Ring Chiralities between Chelating Amine Ligands via Their Prochiral N-Methyl Substituents" @default.
- W2021599578 doi "https://doi.org/10.1021/ic00092a014" @default.
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