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- W2021601045 abstract "Abstract Herein we report on the synthesis of the new strong N‐base and electron donor tdmegb [1,2,4,5‐tetrakis( N , N ′‐dimethylethyleneguanidino)benzene]. Compared to the previously synthesized ttmgb [1,2,4,5‐tetrakis(tetramethylguanidino)benzene], this compound turned out to be a slightly better electron donor and a slightly weaker base. In experiments in which [AuCl(PPH 3 )] was dissolved in CH 3 CN together with tdmegb, we observed the formation of the first cyanomethyl complex of Au, namely [Au(CH 2 CN)(PPh 3 )] in good yield. This reaction does not take place for ttmgb. Moreover, in CH 2 Cl 2 solutions containing the three components [AuCl(PPh 3 )], tdmegb and a nitrile (in large excess), only Au I reduction leading to a [Au 11 Cl 3 (PPh 3 ) 7 ] cluster is observed. Possible reaction mechanisms for this unusual reaction are discussed." @default.
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- W2021601045 date "2010-08-26" @default.
- W2021601045 modified "2023-10-17" @default.
- W2021601045 title "The First Cyanomethyl Complex of Gold, Synthesized by Reaction of a Au <sup>I</sup> Complex with Acetonitrile in the Presence of a New Guanidine N‐Superbase" @default.
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- W2021601045 doi "https://doi.org/10.1002/ejic.201000691" @default.
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