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- W2021613977 abstract "Binding energies and configurations of chiral hydrocarbons adsorbed on stepped Pt surfaces are calculated using Monte Carlo simulations. McFadden et al. have recently shown that many stepped single-crystal surfaces have chiral characteristics and that chiral molecules adsorbed on these surfaces should display enantiospecific properties [McFadden, C. F.; Cremer, P. S.; Gellman, A. J. Langmuir 1996, 12, 2483]. The results presented here provide the first theoretical predictions of this phenomenon by measuring enantiomeric shifts in the binding energies of chiral hydrocarbons on chiral Pt surfaces. Multiple examples of enantiomeric shifts that should be readily detectable using temperature-programmed desorption experiments are identified. The role of adsorbate size and surface structure on the magnitude of enantiomeric shifts in binding energies is discussed." @default.
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- W2021613977 date "1998-02-01" @default.
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- W2021613977 title "Adsorption of Chiral Hydrocarbons on Chiral Platinum Surfaces" @default.
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- W2021613977 doi "https://doi.org/10.1021/la9708546" @default.
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