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- W2021619999 abstract "Abstract The modifications caused by the addition agents dextrin, glucose, l -serine, β-alanine and glycine during the electrodeposition of Ni-Mn-Zn alloy have been investigated as a function of various plating variables. The electrolytic bath contained 20 g l -1 nickel sulphate, 80 g l -1 manganese sulphate, 20 g l -1 zinc sulphate, 30 g l -1 ammonium sulphate, 18 g l -1 thiourea and 0.8 g l -1 ascorbic acid. Bright light grey, smooth and unevenly fine-grained deposits were generally formed in all cases except for β-alanine which gave blackish-grey, uneven and coarsely crystalline deposits. The nickel content in the deposits was found to increase with the addition of dextrin, glucose or l -serine and was decreased on adding β-alanine or glycine to the bath. In contrast, the zinc content followed the reverse trend under similar conditions. The percentage of manganese, however, was always smaller when glucose, β-alanine or glycine were added to the bath but was greater with the addition of dextrin or l -serine. Further, the alloy composition also changed with increasing concentration of these agents. The cathode current efficiency was found to increase linearly in each case as the current density was increased and remained almost unaffected by the presence of the above additives at a given current density. Dextrin, glucose and l -serine were observed to lower the cathode polarization at a given current density; β-alanine and glycine caused the values for the throwing power polarization to increase. Comparatively large values for the throwing power were thus obtained when dextrin, glucose or l -serine was added to the bath. Attempts have been made to explain the results on the basis of adsorption and other theoretical aspects of electrodeposition." @default.
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- W2021619999 date "1986-06-01" @default.
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- W2021619999 title "The role of addition agents in the electrodeposition of Ni-Mn-Zn alloys from a sulphate bath" @default.
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- W2021619999 doi "https://doi.org/10.1016/0257-8972(86)90052-6" @default.
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