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- W2021620413 abstract "The asymmetric unit in the structure of the title compound, [K 2 (C 9 H 4 O 9 S)(H 2 O) 2 ] n , consists of two eight-coordinated K I cations, one 2,4-dicarboxy-5-sulfonatobenzoate dianion (H 2 SBTC 2− ), one bridging water molecule and one terminal coordinated water molecule. One K I cation is coordinated by three carboxylate O atoms and three sulfonate O atoms from four H 2 SBTC 2− ligands and by two bridging water molecules. The second K I cation is coordinated by four sulfonate O atoms and three carboxylate O atoms from five H 2 SBTC 2− ligands and by one terminal coordinated water molecule. The K I cations are linked by sulfonate groups to give a one-dimensional inorganic chain with cage-like K 4 (SO 3 ) 2 repeat units. These one-dimensional chains are bridged by one of the carboxylic acid groups of the H 2 SBTC 2− ligand to form a two-dimensional layer, and these layers are further linked by the remaining carboxylate groups and the benzene rings of the H 2 SBTC 2− ligands to generate a three-dimensional framework. The compound displays a photoluminescent emission at 460 nm upon excitation at 358 nm. In addition, the thermal stability of the title compound has been studied." @default.
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- W2021620413 date "2013-09-06" @default.
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- W2021620413 title "A three-dimensional polymeric potassium complex of 5-sulfonobenzene-1,2,4-tricarboxylic acid: poly[μ-aqua-aqua-μ<sub>9</sub>-(2,4-dicarboxy-5-sulfonatobenzoato)-dipotassium(I)]" @default.
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- W2021620413 doi "https://doi.org/10.1107/s0108270113024499" @default.
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