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• W2021636855 abstract "Molecular motion of adamantane confined in activated carbon fiber (ACF) with slit-width of 1.1 nm was investigated using solid state 1H, 2H, and 13C NMR analyses. Temperature dependence of the 2H spin-lattice relaxation time revealed that adamantane undergoes rapid isotropic reorientation in ACF that is much faster than in bulk plastic crystal. Temperature dependence of the line width of the 1H NMR spectrum also suggests that adamantane undergoes translational motion in ACF. The single minimum potential profile between adamantane and the pore wall might engender the high mobility of guest adamantane molecules as a “two-dimensional fluid.”" @default.
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• W2021636855 date "2008-09-03" @default.
• W2021636855 modified "2023-09-23" @default.
• W2021636855 title "Specific Molecular Motion of Adamantane Induced by Hydrophobic Nanoslits in ACF as Studied Using Solid-State ¹H, ²H, and ¹³C NMR" @default.
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• W2021636855 doi "https://doi.org/10.1080/15421400802305772" @default.
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